Sodium Methoxide 25 Wt. % Solution 18 LiterSynonym: Sodium methylate
- CAS Number 124-41-4
- Linear Formula CH3ONa
- Molecular Weight 54.02
- Beilstein/REAXYS Number 3592982
- MDL number MFCD00012179
- PubChem Substance ID 24849600
| Vapor Density | 1.1 (vs air) |
| Vapor Pressure |
50 mmHg (20°C) 96 mmHg (25°C) |
| InChI Key | WQDUMFSSJAZKTM-UHFFFAOYSA-N |
| Autoignition Temperature | 878°F |
| concentration | 25 wt. % in methanol |
| Refractive Index | n20/D 1.37 |
| Density | 0.945 g/mL at 25°C |
General descriptionThe product is 25 wt.% solution of sodium methoxide in methanol. Its reaction with unactivated aryl bromides in the presence of copper catalyst under various reaction conditions has been studied. It reacts with aryl halides in the presence of a palladium catalyst in DMF (Dimethylformamide) to afford arenes.
ApplicationA novel high-spin hexanuclear Mn(III) cluster, [NaMn6(OMe)12(dbm)6]+, was synthesized via MnCl2 oxidation with simultaneous NaOMe promoted aggregation. This cluster has an unprecedented cyclic structure and 24 unpaired electrons in its ground state.
Sodium methoxide solution has been used in the synthesis of NO-containing nanoparticles (SNO-NP).
Safety Information
GHS02, GHS05, GHS06, GHS08
Signal word DangerHazard statements H225-H251-H301 + H311 + H331-H314-H370Precautionary statements P210-P235 + P410-P260-P280-P301 + P310-P305 + P351 + P338Supplemental Hazard Statements Reacts violently with water.RIDADR UN1289 – class 3 – PG 2 – Sodium methylate solutionsWGK Germany 1Flash Point(F) 51.8°FFlash Point(C) 11°C
DocumentsSafety Data Sheet
Warnings
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